Copper-catalyzed oxygen atom transfer of N-oxides leading to a facile deoxygenation procedure applicable to both heterocyclic and amine N-oxides.
نویسندگان
چکیده
Deoxygenation of various types of N-oxides including both heterocyclic and alkyl(aryl)amine derivatives has successfully been developed by the copper-catalyzed oxygen atom transfer using diazo compounds as the oxygen acceptor. The reaction proceeds smoothly over a broad range of substrates with excellent functional group tolerance under mild conditions.
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Article history: Received 3 November 2008 Revised 2 December 2008 Accepted 9 December 2008 Available online 16 December 2008
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 32 شماره
صفحات -
تاریخ انتشار 2015